Erratum: Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts
نویسندگان
چکیده
منابع مشابه
Crystallographic Structure Determination of MFI-Zeolite Nanosheets
Ultrathin MFI-zeolite nanosheets can be packed on porous supports to create molecular sieve membranes. The nanosheets on porous support reduce morphological damage seen in regular MFIzeolite crystals [1]. MFI-zeolite belongs to pentasil family of zeolites where the periodic building unit (PerBU) is composed of 12 interconnected SiO4 tetrahedral (T12) units of 41m2 (D2d) symmetry [2]. Rotation o...
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Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yiel...
متن کامل2D Zeolite Coatings: Langmuir-Schaefer Deposition of 3 nm Thick MFI Zeolite Nanosheets.
Stable suspensions of zeolite nanosheets (3 nm thick MFI layers) were prepared in ethanol following acid treatment, which partially removed the associated organic structure-directing agent. Nanosheets from these suspensions could then be dispersed at the air-water interface and transferred to silicon wafers using Langmuir-Schaefer deposition. Using layer-by-layer deposition, control on coating ...
متن کاملMFI zeolite nanosheets with post-synthetic Ti grafting for catalytic epoxidation of bulky olefins using H2O2.
The external surfaces of the surfactant-directed, 2.5 nm MFI zeolite nanosheets were grafted with Ti using titanium(IV) butoxide. The Ti/MFI nanosheets exhibited a remarkable catalytic performance for epoxidation of bulky olefins using H2O2 as an oxidant, in comparison to the mesoporous silicas with amorphous frameworks.
متن کاملSynthesis and characterization of MFI zeolite nanosheets for optimizing the dominant operational conditions of methanol to propylene process
Nanosheets of MFI zeolite were successfully synthesized by hydrothermal method and were properly characterized by XRD, FE-SEM, EDX-dot mapping, TEM, FT-IR, N2 adsorption/desorption, NH3-TPD, ICP-AES and TGA techniques. The characterizations of MFI zeolite nanosheets suitably confirmed well synthesized MFI nanostructure, superior specific surface area (695.96m2.g-1) and great mesopores volume. C...
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ژورنال
عنوان ژورنال: Nature
سال: 2009
ISSN: 0028-0836,1476-4687
DOI: 10.1038/nature08493